排序方式: 共有66条查询结果,搜索用时 265 毫秒
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以麦芽酚或乙基麦芽酚为起始原料,经乙酰化、钯碳氢化、羰基α位乙酰氧化和脱乙酰基等4步反应,合成了两种双羟基吡喃酮化合物。利用核磁共振氢谱、碳谱和高分辨质谱对每一步反应产物进了结构表征,优化了合成反应工艺,并通过清除自由基反应对化合物的抗氧化活性进行了测试。结果表明,双羟基吡喃酮化合物对ABTS+?、DPPH?和galvinoxyl?三种自由基清除率分别达到88.9%、83.8%和68.4%,明显高于维生素E和2,6-二叔丁基对甲酚的自由基清除率,表现出优异的抗氧化活性。构效关系研究表明,在吡喃酮结构中引入羟基或增强侧链取代基的给电子能力均能提高化合物清除自由基的能力,为新型抗氧化剂的合成开发提供了参考。 相似文献
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Tuan-Anh Nguyen Tae-Sun Jun Muhammad Rashid Yong Shin Kim 《Materials Letters》2011,65(17-18):2823-2825
Mesoporous tungsten oxide nanofibers were synthesized via a 500 °C thermal treatment of composite nanofibers prepared by electrospinning an ethanol solution consisting of tungsten ethoxide, P123 triblock copolymer, and polyvinylpyrrolidone. The as-electrospun composites exhibited unwoven nanofibers with an average diameter of 233 nm and a smooth surface morphology. During the calcination process, the composite nanofibers were shrunk to 85 nm in diameter and converted into rough, wormhole-like nanofibers. These were formed by agglomerating polycrystalline WO3 particles of 10–30 nm along the axial direction. Furthermore, a measured pore-size distribution indicated that this nanofiber mat had different types of meso-sized porosities, which may have resulted from their wormhole-like structures and inter-fiber voids. In addition, it was observed to have the intra-grain porosity with the diameter of about 1.0 nm. 相似文献
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《Journal of the European Ceramic Society》2023,43(13):5616-5625
YAG ceramic fiber is the preferred material for the gain medium of the new generation fiber laser. However, the fabrication of hundred-micron and defect-free YAG ceramic fibers is still the primary challenge. In this paper, YAG ceramic fibers with the diameter of 147 µm and length of 113 mm were successfully batch fabricated by the combination of gelcasting and mold design, and the diameter fluctuation rate was only 1.4%. The solid loading of the slurries (46–54 vol%) were systematically investigated to achieve high density and net-shape forming of green fibers. It was found that the YAG ceramic fiber was highly transparent with the optimized solid loading of 52 vol%, and the transmittance of the YAG ceramic (2 mm thick) at 800 nm was 82.6%. Its bending strength was as high as 1124 ± 86 MPa. The ideas and methods of this study will promote the development of gelcasting in the field of hundred-micron ceramic fibers. 相似文献
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为考察电子烟烟液的含水率、丙二醇与丙三醇比例、烟碱浓度和电子烟烟具输出功率对气溶胶中醛类化合物的影响,采用高效液相色谱法,将实验室配制的烟液填充至可填充式电子烟内,按照抽吸容量55 mL、抽吸频率30 s、抽吸持续时间3 s的模式抽吸50口,测定电子烟气溶胶中的甲醛、乙醛和丙烯醛的释放量。结果表明:①甲醛主要源于丙三醇的裂解,乙醛主要源于丙二醇的裂解,丙烯醛主要源于较高温度条件下丙三醇的脱水。②醛类化合物的释放量随烟碱浓度的升高而降低,随烟具输出功率的升高而增加。③含水率对醛类化合物释放量的影响较小。 相似文献
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为明确不同产区影响上部烟叶内在品质的关键外观指标,制备我国5个生态二级区上部烟叶品质梯度样品,对不同生态区上部烟叶外观特征与感官品质、外观特征与化学成分间的相互关系进行分析。结果表明:①不同生态区上部烟叶的多数外观特征指标分值差异显著。②在一定范围内,上部烟叶随颜色加深,香气饱满程度提升,总氮含量(质量分数)增加,糖碱比值、糖含量和淀粉含量下降;随柔软度改善、油润感增强或身份趋于中等,香气质感和口感舒适程度改善,糖含量和糖碱比值升高。③随机森林特征贡献率分析发现,豫中和豫西生态区影响上部烟叶感官品质的关键外观特征指标为身份、油润感和成熟度,湘南生态区为叶片结构、身份和颜色深浅,滇东生态区为柔软度、叶片结构和颜色深浅,渝东南生态区为油润感、叶片结构和成熟度。影响上部烟叶感官品质的关键外观指标在不同生态区间存在差异。 相似文献
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为解决传统滚筒加料系统加料均匀性差、料液有效利用率低和物料粘附等问题,根据薄层物料双面加料更加均匀的原理,研制了薄层物料双面喷射式加料系统。该系统主要由松散均布、高速摊薄、双面多点喷射加料和过滤吸附等装置组成。通过对物料进行摊薄,形成稳定的物料帘,在物料帘的双面实施多点喷射加料,保证料液施加的均匀性;通过排潮抽吸风使悬浮的雾化料液穿过物料层,利用物料层的吸附过滤作用,提高料液的利用率;加料腔为不对称多孔罩式结构,使腔体内外气压保持平衡,减少物料与腔壁的接触。利用"黄金叶(硬帝豪)"对双面喷射加料和滚筒加料两种方式的加工品质、产品质量、主流烟气成分和能耗物耗进行对比试验。结果表明,与滚筒加料方式相比,采用薄层物料双面喷射加料方式,加料精度为0.08%,加料均匀系数提高1.69百分点,料液有效利用率提高13.7百分点,物料粘附量减少4.1 kg/批次;卷烟感官质量提高0.5分;综合加工成本节约6.97元/箱。该系统有效提高了片烟加料的均匀性和料液有效利用率,避免了物料粘附现象,改善了卷烟感官质量,节约了能源和原材料消耗。 相似文献